Generation of Singlet Oxygen from Fragmentation of Monoactivated 1,1-Dihydroperoxides
نویسندگان
چکیده
منابع مشابه
Generation of singlet oxygen from fragmentation of monoactivated 1,1-dihydroperoxides.
The first singlet excited state of molecular oxygen ((1)O(2)) is an important oxidant in chemistry, biology, and medicine. (1)O(2) is most often generated through photosensitized excitation of ground-state oxygen. (1)O(2) can also be generated chemically through the decomposition of hydrogen peroxide and other peroxides. However, most of these "dark oxygenations" require water-rich media associ...
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Monoactivated derivatives of 1,1-dihydroperoxides undergo an unprecedented base-promoted fragmentation to efficiently generate singlet oxygen (1O2) in anhydrous organic solvents.
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2012
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo202265j